Ownership Submission
FORM 4
Check this box if no longer subject to Section 16. Form 4 or Form 5 obligations may continue. See Instruction 1(b).
UNITED STATES SECURITIES AND EXCHANGE COMMISSION
Washington, D.C. 20549

STATEMENT OF CHANGES IN BENEFICIAL OWNERSHIP OF SECURITIES

Filed pursuant to Section 16(a) of the Securities Exchange Act of 1934, Section 17(a) of the Public Utility Holding Company Act of 1935 or Section 30(h) of the Investment Company Act of 1940
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(Print or Type Responses)
1. Name and Address of Reporting Person *
DEMCHAK WILLIAM S
  2. Issuer Name and Ticker or Trading Symbol
PNC FINANCIAL SERVICES GROUP INC [PNC]
5. Relationship of Reporting Person(s) to Issuer
(Check all applicable)
_____ Director _____ 10% Owner
__X__ Officer (give title below) _____ Other (specify below)
Vice Chairman
(Last)
(First)
(Middle)
ONE PNC PLAZA, 249 FIFTH AVENUE
3. Date of Earliest Transaction (Month/Day/Year)
11/07/2006
(Street)

PITTSBURGH, PA 15222-2707
4. If Amendment, Date Original Filed(Month/Day/Year)
6. Individual or Joint/Group Filing(Check Applicable Line)
_X_ Form filed by One Reporting Person
___ Form filed by More than One Reporting Person
(City)
(State)
(Zip)
Table I - Non-Derivative Securities Acquired, Disposed of, or Beneficially Owned
1.Title of Security
(Instr. 3)
2. Transaction Date (Month/Day/Year) 2A. Deemed Execution Date, if any (Month/Day/Year) 3. Transaction Code
(Instr. 8)
4. Securities Acquired (A) or Disposed of (D)
(Instr. 3, 4 and 5)
5. Amount of Securities Beneficially Owned Following Reported Transaction(s)
(Instr. 3 and 4)
6. Ownership Form: Direct (D) or Indirect (I)
(Instr. 4)
7. Nature of Indirect Beneficial Ownership
(Instr. 4)
Code V Amount (A) or (D) Price
$5 Par Common Stock 11/07/2006   M(1)   36,229 A $ 43.81 287,541 D  
$5 Par Common Stock 11/07/2006   F(1)   22,781 D $ 69.67 264,760 D  
$5 Par Common Stock 11/07/2006   F(1)   5,731 D $ 69.67 259,029 D  
$5 Par Common Stock 10/24/2006   J(2) V 210 A (3) 695 I 401(k) Plan

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Table II - Derivative Securities Acquired, Disposed of, or Beneficially Owned
(e.g., puts, calls, warrants, options, convertible securities)
1. Title of Derivative Security
(Instr. 3)
2. Conversion or Exercise Price of Derivative Security 3. Transaction Date (Month/Day/Year) 3A. Deemed Execution Date, if any (Month/Day/Year) 4. Transaction Code
(Instr. 8)
5. Number of Derivative Securities Acquired (A) or Disposed of (D)
(Instr. 3, 4, and 5)
6. Date Exercisable and Expiration Date
(Month/Day/Year)
7. Title and Amount of Underlying Securities
(Instr. 3 and 4)
8. Price of Derivative Security
(Instr. 5)
9. Number of Derivative Securities Beneficially Owned Following Reported Transaction(s)
(Instr. 4)
10. Ownership Form of Derivative Security: Direct (D) or Indirect (I)
(Instr. 4)
11. Nature of Indirect Beneficial Ownership
(Instr. 4)
Code V (A) (D) Date Exercisable Expiration Date Title Amount or Number of Shares
Employee Stock Option (Right-to-Buy) $ 43.81 11/07/2006   M     36,229 01/03/2004 01/03/2013 $5 Par Common Stock 36,229 $ 0 0 D  
Employee Stock Option (Right-to-Buy) Reload Option $ 69.67 11/07/2006   A   28,512   11/07/2007 01/03/2013 $5 Par Common Stock 28,512 $ 0 28,512 D  
Phantom Stock Unit (4) 10/24/2006   J(5) V 647     (6)   (6) $5 Par Common Stock 647 (7) 27,710 I Deferred Compensation Plan
Phantom Stock Unit (4) 10/24/2006   J(5) V 48     (6)   (6) $5 Par Common Stock 48 (8) 2,048 I Supplemental Incentive Savings Plan

Reporting Owners

Reporting Owner Name / Address Relationships
 Director  10% Owner  Officer  Other
DEMCHAK WILLIAM S
ONE PNC PLAZA
249 FIFTH AVENUE
PITTSBURGH, PA 15222-2707
      Vice Chairman  

Signatures

 Lori A. Hasselman, Attorney-in-Fact for William S. Demchak   11/09/2006
**Signature of Reporting Person Date

Explanation of Responses:

* If the form is filed by more than one reporting person, see Instruction 4(b)(v).
** Intentional misstatements or omissions of facts constitute Federal Criminal Violations. See 18 U.S.C. 1001 and 15 U.S.C. 78ff(a).
(1) The exercise of this option and the satisfaction of the resulting tax withholding obligation were effected by the Reporting Person through the delivery, via attestation, of already owned shares of common stock of the Issuer and did not involve an open market transaction in the Issuer's securities.
(2) Shares acquired under the PNC Incentive Savings Plan, including shares acquired through reinvestment of dividends.
(3) Shares acquired under the PNC Incentive Savings Plan at various prices ranging from $63.67 to $72.77.
(4) 1 for 1.
(5) Dividend reinvestment shares acquired.
(6) Phantom Stock Units will be settled in cash upon distribution from the reporting person's plan account and generally do not expire.
(7) Dividend reinvestment shares acquired under the PNC Deferred Compensation Plan at various prices.
(8) Dividend reinvestment shares acquired under the PNC Supplemental Incentive Savings Plan at various prices.

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